Encapsulation of Organic Dyes within an Electron‐Deficient Redox Metal‐Organic Tetrahedron for Photocatalytic Proton Reduction

Abstract

AbstractThe design of artificial systems that mimic highly evolved and finely tuned natural photosynthetic systems is a subject of intensive research. By incorporating electron‐deficient anthraquinone within the ligand backbone, a redox‐active Ni‐based tetrahedron was developed as a redox vehicle for the construction of an artificial photosynthesis system. The tetrahedron can encapsulate fluorescein within its cavity for light‐driven H2 evolution, with the turnover number reaching 1200 moles H2 per mole redox catalyst. This well‐designed supramolecular system displayed a significantly superior activities compared with the reference mononuclear compound or introducing an inactive inhibitor (ATP), which confirmed this enzymatic photocatalytic behaviour.