Encapsulating perovskite solar cells for long-term stability and prevention of lead toxicity

Abstract

Lead halide perovskite solar cells (PSCs) have achieved remarkable efficiencies comparable to those of their established silicon counterparts at a very fast pace. Moreover, solution-processable facile technologies offer low-cost, low-temperature, scalable fabrication of these solar cells. Numerous studies have focused on improving the performance, stability, and processing of PSCs. However, potential lead toxicity and poor long-term stability impede their commercialization. In recent years, several studies have developed novel encapsulants for PSCs that can simultaneously improve stability and impede potential lead leakage. Although improvements have been made on both fronts, no solution to date could achieve a level of stability and leakage prevention that could result in a market breakthrough. Here, we analyze PSC encapsulation and lead leakage prevention techniques undertaken in recent years. While most of the related studies focused on improving either stability or toxicity, we note that both can be solved together with a suitable encapsulant that is impermeable to both moisture and Pb2+ ions. In addition, the lack of a unified standard stability testing protocol has led to stability testing under a variety of temperatures, humidities, and environmental conditions. Therefore, the urgency for a standard protocol for stability and lead toxicity testing cannot be overlooked.