Encapsulated crystallisation inhibitor as a long-term solution to mitigate salt damage in hydraulic mortars

Abstract

Salt (NaCl) weathering in mortar, can be mitigated by incorporating a crystallisation inhibitor (sodium ferrocyanide) during mortar preparation. However, the service-life of the inhibitor is limited, due to its susceptibility to leaching out of mortar. Encapsulating the inhibitor in chitosan-calcium alginate capsules has demonstrated controlled-release of the inhibitor and therefore, reduction in its leaching. Nevertheless, the addition of capsules may have a negative effect on mortar's properties and/or its salt-weathering resistance. In this research, natural hydraulic lime (NHL) and commercial cement-based mortars were prepared, with encapsulated inhibitor and with directly mixed-in inhibitor. Mechanical and physical properties of mortars were assessed experimentally. An accelerated NaCl-weathering test was performed to assess the durability of mortar to salt damage. The damage evolution was assessed visually and by quantifying material loss, efflorescence and leaching of the inhibitor. At the end of the test, crystal morphology inside the pores was examined using SEM. The results show that adding inhibitor, both in encapsulated and mixed-in form, had a negligible effect on the properties of NHL and cement-based mortars. Compared to the reference mortar without inhibitor, NHL-mortars with mixed-in inhibitor and encapsulated inhibitor had a better durability to salt damage, showing negligible material loss. The capsules facilitated controlled-release and reduced leaching of the inhibitor. In cement-based mortars including the reference, no damage was observed; still, the inhibitor was shown to be effective in modifying the salt crystal habit. The results show that encapsulation of the inhibitor can improve the service-life of the mortar without compromising its performance.