Abstract

The low energy release efficiency seriously hinders the application of Boron (B) powder as metal fuel in solid propellants. To overcome this issue, a series of B-based spherical composites were produced by encapsulating B-based metastable intermixed composites (MICs) with ammonium perchlorate (AP) by a solvent evaporation-induced self-assembly (EISA) method in this work. A self-developed combustion system containing an ignition pool, indicator light, and high-speed camera to precisely monitor ignition delay and burning times was utilized. The EISA-prepared B/Bi2O3/AP spherical composites showed higher combustion temperature (1435 °C) and shorter ignition delay time (379 ± 25 ms) than the physically mixed sample (1264 °C and 1035 ± 63 ms). The isolated reaction units of spherical B/Bi2O3/AP composite accelerated heat transfer and accumulation and reduced sintering and agglomeration, thus promoting the combustion efficiency of B powder. This study presents a promising strategy by doping and encapsulating process to increase the combustion performance of B-based metal fuel.

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