Abstract
This review collects the major progress in the field of enantioselective transformations promoted by chiral vanadium catalysts, covering the literature since the beginning of 2015, illustrating the power of these catalysts to provide various types of reactions. • Enantioselective vanadium-catalyzed oxidative couplings. • Asymmetric sulfoxidations with chiral vanadium catalysts. • Chiral vanadium catalysts in epoxidations. • Cyanosilylations of aldehydes promoted by chiral vanadium complexes. • Vanadium in enantioselective domino reactions.
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