Abstract
Regardless of whether SAMP or RAMBO (or their enantiomers RAMP or SAMBO) are used, the asymmetric synthesis of N-protected β-amino sulfones 4 by conjugate addition of a chiral nitrogen nucleophile (S)-1 (SAMP) or (R,R,R)-2 (RAMBO) to (E)-alkenyl sulfones 3 proceeds with high enantiomeric excesses. The title compounds are obtained after removal of the chiral auxiliary by reductive N−N bond cleavage.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
