Abstract
The enantiomers of the highly lipophilic α-amino acid m-carboranyl-alanine [3-(1,7-dicarba- closo-dodecaborane(12)-1-yl)-2-aminopropanoic acid], a carborane containing analogue of phenylalanine, have been synthesised via hydroxyamination of the N-acyl derivative formed from 3-( m-carboranyl)propionic acid [3-(1,7-dicarba- closo-dodeca-borane(12)-1-yl)-2-propanoic acid] and Oppolzer's camphor sultam. The enantiomeric excess of both enantiomers of the amino acid was >98%. ( S)-Configuration was assigned to the (+)-enantiomer (CH 3OH, 589 nm).
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