Abstract
AbstractWe report herein a highly enantioselective synthesis of multisubstituted biaryl chlorides/iodides by sequential halogenation reactions (desymmetrization/kinetic resolution sequence). The selectivity of biaryl chlorides/iodides obtained in the first asymmetric reaction (desymmetrization) could be enhanced by the kinetic resolution‐type asymmetric bromination to afford the corresponding chiral biaryl chlorides/iodides in excellent selectivities (up to 99 % ee).magnified image
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