Abstract
The first asymmetric condensation of prochiral silacyclohexanones with hydroxylamines is developed by chiral phosphoric acid catalysis, which provided a facile and straightforward protocol for the enantioselective construction of valuable axially chiral silacyclohexylidene oxime ethers that are otherwise inaccessible. Notably, this constitutes a rare example for accessing silacycles featuring an axial chirality.
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