Abstract
AbstractA sequence of reactions that include an iridium‐catalyzed regio‐ and enantioselective allylic amination, the formation of an amide, a ruthenium‐catalyzed ring‐closing metathesis, and an intramolecular Heck reaction allows for the preparation of [3,3,1]‐ and [4,3,1]‐bicyclic amides. The target compounds have a nitrogen atom at the bridgehead, a nonplanar amide moiety, and a stereogenic center at the one‐carbon bridge.
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