Abstract

We have synthesized minor groove imidazole functionalized (S)-BINOL from (S)-BINOL. The molecule has been designed in such a way that this molecule introduces new opportunities in the field of chiral recognition and Cu(II) sensing. The developed sensor has high selectivity for Cu(II) among the metal ions tested by fluorescence turn off manner. The fluorescence chiral discrimination towards unmodified α-aminoacids has been studied for the in situ generated Cu(II) complex of 1 which shows remarkable results. The ligand displacement mechanism can be attributed for the fluorescent chiral discrimination.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.