Abstract
AbstractIns kühle Nass: Bei der ersten Lewis‐Säure‐katalysierten asymmetrischen Friedel‐Crafts‐Alkylierung mit Olefinen in Wasser genügen schon 0.15 Mol‐% eines DNA‐Kupfer‐Katalysators, um in der Reaktion von α,β‐ungesättigten 2‐Acylimidazolen mit heteroaromatischen π‐Nucleophilen gute Ausbeuten und Enantioselektivitäten zu erzielen (siehe Schema; dmbpy=4,4′‐Dimethyl‐2,2′‐bipyridin).magnified image
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