Abstract
Polypyrroles substituted by chiral side chains have been electrochemically deposited on platinum from acetonitrile solutions in the presence of lithium perchlorate, tetraemyhammonium perchlorate, tetrabutylammonium perchlorate, tetraethylammonium tetrafluoroborate and tetramethylammonium hexafluorophosphate. The electrodes exhibited a good redox reversibility, long-term stability and were stable over a wide potential range (−3.0 to + 1.2 V versus Ag/0.01 M AgNO 3). The enantioselective recognition properties were investigated in the presence of the enannomers of camphorsulfonic acid as supporting electrolyte and doping agem. The coated electrodes are also capable of being used as asymmetric inducator for the electrochemical rediation of prochiral organic molecules.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
