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Abstract
Substituted chiral thiophene 1-oxides and their cycloadducts of variable enantiopurity have been isolated as products of dioxygenase-catalysed sulfoxidation of the corresponding thiophenes using intact cells of Pseudomonas putida; thermal racemization (ΔG‡= 25.1 kcal mol–1) of the enantiopure metabolite (1R)-2-methylbenzo[b]thiophene 1-oxide has been observed.
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