Abstract
Reported is an efficient method for the synthesis of hexahydro-1H-benz[f]indoles. The asymmetric intramolecular alkene carboamination is achieved using a chiral copper PhBOX complex as catalyst. Good yields and enantioselectivities can be obtained in a variety of products with vicinal tertiary and quaternary carbon stereocenters. Various nitrogen-protecting groups are also tolerated for this method.
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