Abstract
AbstractIodido(binaphtholato)samarium catalyzes the Michael addition of aromatic amines to N‐alkenoyloxazolidinones affording β‐amino acid derivatives with enantiomeric excesses of up to 88 %. A study of the effect of temperature on the asymmetric induction revealed an isoinversion in two reactions. The observation of a non‐linear effect suggests an equilibrium between several active species including dimers.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
