Abstract
Abstract A chiral diphosphinite: methyl 4,6-O-benzylidene-2,3-bis-O-diphenylphosphino-β-d-glucopyranoside (β-POOP) was derived from d-glucose. High enantiomeric excess values of up to 91% were achieved in the hydrogenation of α-acetamidoacrylic acids using the rhodium complex of β-POOP.
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