Abstract

Abstract A supramolecular bilayer assembly, composed of a cationic peptide lipid having an (S)-alanine residue, an additional one having an (S)-binaphthol moiety, a hydrophobic pyridoxamine derivative, and copper(II) ions, performed substrate-selective catalysis as a vitamin B6-dependent artificial aminotransferase to transform α-keto acids into the corresponding α-amino acids in an enantiomeric excess of the d-isomer.

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