Abstract
Aus der Luft gegriffen: Die hoch enantioselektive Oxidation von 3,4-substituierten meso-Pyrrolidinen zu Δ1-Pyrrolinen wird beschrieben. Die Reaktion wird durch die Monoaminoxidase aus Aspergillus niger (MAO-N D5) katalysiert und verwendet molekularen Sauerstoff aus der Luft als stöchiometrisches Oxidationsmittel. Die Δ1-Pyrroline dienen als Bausteine für die Synthese von L-Prolin-Analoga und α-Aminonitrilen mit hoher Enantiomerenreinheit. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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