Abstract

AbstractA series of air‐stable chiral ferrocenylphosphines (LB1–LB4) were prepared and used in the asymmetric allylic substitution of Morita–Baylis–Hillman (MBH) adducts with phthalimide under mild reaction conditions; the (R,SFc)‐ferrocenylphosphine LB4 afforded the desired amination products 3 in moderate yields with excellent enantioselectivities. The absolute configuration of 3o was confirmed by X‐ray analysis.

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