Abstract
Chiral (phosphinophenyl-oxazoline)palladium complexes have been studied as enantioselective catalysts for allylic amination using benzylamine or the sodium salts of p-toluenesulfonamide, benzoylhydrazine, and (Boc) 2NH as nucleophiles. In the reactions with 1,3-diphenyl- and 1,3 -dialkyl-2-propenyl acetates, carbonates, or phosphates, moderate to high enantiomeric excesses of up to 97% have been obtained.
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