Abstract
AbstractTetraol‐protected α‐chiral allylboronates are utilized in diastereo‐ and enantioselective transformations of cyclic imines (up to 98 %, d.r. 97 : 3, e.r. 99 : 1). An application to in situ formed N‐unsubstituted imines gives in a consecutive one‐pot sequence selective access to all four stereoisomers of the homoallylamine within minutes (up to 88 %, d.r. 81 : 19, e.r. 99 : 1). These results underline the usability, tuneability and stability of tetraol‐based allylboronates.
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