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Abstract
The first enantioselective reaction of acyclic α‐ketiminoesters with thiols has been developed. Good yields and enantioselectivities were obtained using our original cinchona alkaloid amide/zinc(II) catalysts. The obtained products were converted into useful chiral thiazolidines. Based on experimental results and DFT calculation, transition states were proposed to explain the stereoselectivity of the reaction.
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