Abstract
AbstractA designed chiral thiourea‐iminophosphorane catalyst was developed to afford α‐acyloxythioesters through enantioselective acyl‐transfer/protonation of α‐acyloxy‐β‐ketosulfides. The desired reaction proceeded in good yields with high enantioselectivities using a chiral thiourea‐iminophosphorane bearing a pyrrolidine scaffold.
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