Abstract
The catalytic enantioselective and diastereoselective Michael addition reactions promoted by chiral bifunctional organocatalysts are described. The treatment of α-cyanoketones with nitroalkenes under mild reaction conditions afforded the corresponding γ-niro α-cyanoketones with excellent diastereoselectivities (up to syn/anti >99/1) and excellent enantioselectivities (up to 99% ee).
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