Enabling resonant ultrasound spectroscopy in extreme environments

Abstract

Elastic moduli are fundamental thermodynamic susceptibilities that connect to thermodynamics, electronic structure, and mechanic properties. Thus, determining the changes of elastic moduli as a function of time or temperature is a powerful tool to study several thermodynamic and materials phenomena. Resonant Ultrasound Spectroscopy (RUS) determines elastic constants with high accuracy and precision from a single measurement of the mechanical resonances of a sample. Conventionally, the quantitative extraction of elastic moduli with RUS assumes free boundary conditions but lead to unstable positioning of the sample making it incompatible with extreme environments like high magnetic fields. In practice, even holding the sample produces contact forces that deviate from free-boundary conditions shifting resonant frequencies. In this talk, we show that, we can reduce the free-boundary conditions (by gluing/adhering the sample to the transducer), while still being able to obtain the full elastic tensor by a simple model of the sample-transducer interaction. This means elastic constants can be determined to within the uncertainty of conventional RUS, but with significant improvements in sample stability and control of sample orientation. We show the results of studying of several magnetic and structural phase-transitions using this new method.