(E)-N-(4-{[1-(Prop-2-en-1-yl)-1H-1,2,3-triazol-4-yl]meth-oxy}benzyl-idene)morpholin-4-amine.

Mehmet Akkurt,Pezhman Shiri,Namık Özdemir,Mehdi Mohammadi Chermahini,Aliasghar Jarrahpour

doi:10.1107/s1600536814002827

Mehmet Akkurt, Pezhman Shiri + Show 3 more

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https://doi.org/10.1107/s1600536814002827

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Abstract

The asymmetric unit of the title compound, C17H21N5O2, contains two crystallographically independent molecules, which are linked by a C—H⋯N hydrogen bond. The morpholine rings of both molecules adopt distorted chair conformations. The dihedral angles between the triazole and benzene rings are 12.8 (3)° in the first independent molecule in which the –N=C– group between the morpholine and benzene rings is disordered [site-occupancy ratio = 0.576 (7):0.424 (7)] and 88.1 (2)° in the second independent molecule. In the crystal, molecules are linked by C—H⋯N hydrogen bonds along the [100] direction. In addition, one weak C—H⋯π interaction and two weak π–π stacking interactions [centroid–centroid distances = 3.840 (3) and 3.823 (2) Å] between the triazole rings of adjacent molecules are observed. The atoms of the terminal propenyl groups in both molecules are disordered over two sets of sites [site-occupancy ratios = 0.691 (10):0.309 (10) and 0.705 (15):0.295 (15)].

Highlights

The asymmetric unit of the title compound, C17H21N5O2, contains two crystallographically independent molecules, which are linked by a C—H N hydrogen bond
The dihedral angles between the triazole and benzene rings are 12.8 (3) in the first independent molecule in which the –N C– group between the morpholine and benzene rings is disordered [site-occupancy ratio =
The atoms of the terminal propenyl groups in both molecules are disordered over two sets of sites [siteoccupancy ratios = 0.691 (10):0.309 (10) and 0.705 (15): 0.295 (15)]

Summary

Structure Reports

The asymmetric unit of the title compound, C17H21N5O2, contains two crystallographically independent molecules, which are linked by a C—H N hydrogen bond. The morpholine rings of both molecules adopt distorted chair conformations. The dihedral angles between the triazole and benzene rings are 12.8 (3) in the first independent molecule in which the –N C– group between the morpholine and benzene rings is disordered [site-occupancy ratio =. 0.576 (7):0.424 (7)] and 88.1 (2) in the second independent molecule. Molecules are linked by C—H N hydrogen bonds along the [100] direction. 3.823 (2) Å] between the triazole rings of adjacent molecules are observed. The atoms of the terminal propenyl groups in both molecules are disordered over two sets of sites [siteoccupancy ratios = 0.691 (10):0.309 (10) and 0.705 (15): 0.295 (15)]

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Namık Özdemir

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