Employing waste to manage waste: Utilizing waste biomaterials for the elimination of hazardous contaminant [Cr(VI)] from aqueous matrices

Abstract

Pollution caused due to discharge of toxic and hazardous chemical contaminants from industrial processes is an issue of major environmental concern. Hexavalent chromium [Cr(VI)] is one such known toxic heavy metal contaminant emanated largely from various industrial processes. Since physical-chemical treatment techniques are beset with several problems, there is an increased attention on the use of waste biomaterials/biomass as sorbents for the elimination of heavy metals from aqueous matrices. The main purpose of this study was to evaluate the effectiveness of some low-cost waste biomaterials such as fruit wastes, agricultural and industrial waste/byproducts, waste parts of photosynthetic plants, aquatic plants and fungal biomass collected from different sources for the biosorption of Cr(VI) from aqueous matrices. Amid the tested biomaterials, wood apple shell (WAS) biomass (Limonia acidissima) was found to be highly efficient biosorbent for Cr(VI) sorption. In majority of biomass, it was observed that biosorption of Cr(VI) took place at acidic pH with optimum pH ranging from 2.0 to 5.0. Loading capacity of WAS biomass (29.37 mg/g) was higher than that of conventional adsorbent activated charcoal (26.56 mg/g), which was used as control. Cr(VI) treated biomass (WAS) was characterized using instrumental techniques such as Scanned Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) confirmed the adsorption of Cr(VI). Boehm titration and FTIR studies were conducted to ascertain the presence of functional groups responsible for Cr(VI) sorption by WAS biomass. The WAS biomass removed Cr(VI) from industrial wastewater with an efficiency of >99.9% thus complying with the statutory limits. Considering the economical aspect, the selected biomass can be viewed as a potential candidate for the elimination of toxic contaminant from wastewater.