Abstract
Under hydrothermal conditions, in the presence of H2BDC, the self-assembly of CdCl2, H2ip or H2NDC at pH = 7 generated two Cd(II)-containing coordination polymers, Cd6(ip)6(μ-H2O)4·H2O (1) and Cd2(NDC)2(μ-H2O)2 (2) (H2BDC/H2ip/H2NDC = 1,4/1,3/1,2-benzenedicarboxylic acid). The structures are 2D metal-organic frameworks constructed from Cd-O-C rod-shaped SBUs (Secondary Building Units). Crystal samples in the solid state display strong fluorescence at 335 and 343 nm.
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