Empirical estimation of size-resolved scavenging coefficients derived from in-situ measurements at background sites in Korea during 2013–2020

Abstract

Owing to insufficient detailed in-field observations for explaining and quantifying the wet-scavenging coefficients, especially those below-cloud (Λbelow), prediction of accurate aerosol concentrations and/or behaviors in the atmosphere remains challenging. As a pioneering effort, this study focused on establishing an empirical equation for size-resolved Λbelow, which represent the characteristics in Korea, using long-term aerosol number size distribution and meteorological variable measurements at two background sites in Korea (Baengnyeong and Jeju). The median Λbelow values derived from the total number concentrations were 8.06 × 10−6 s−1 for Baengnyeong and 1.04 × 10−5 s−1 for Jeju, which are similar to or slightly lower than the Λbelow reported by previous in-situ studies. These may be caused by differences in the precipitation rates, precipitation drop sizes, aerosol chemical/hygroscopic properties, and aerosol size distributions at the measurement sites. Although the derived parameterization can cover a wide range (10 nm to 10 μm), the derived equation for the fourth-degree polynomial shows a high correlation coefficient of 0.81, indicating that the measured and fitted Λbelow converge within a narrow range. Moreover, the variation in Λbelow is relatively constant for aerosol diameters larger than ∼1 μm, similar to those derived from theoretical equations rather than empirical equations in previous studies. This study is thus expected to contribute to improving the below-cloud scavenging module implemented in a chemical transport model by covering a wide range of aerosol diameters to avoid overestimation by extrapolation of Λbelow.