Abstract

Abstract Little is known about the microstructural behavior of magnetite during hypervelocity impact events, even though it is a widespread accessory mineral and an important magnetic carrier in terrestrial and extraterrestrial rocks. We report systematic electron backscatter diffraction crystallographic analysis of shock features in magnetite from a transect across the 52-km-diameter ca. 380 Ma Siljan impact structure in Sweden. Magnetite grains in granitoid samples contain brittle fracturing, crystal-plasticity, and lamellar twins. Deformation twins along {111} with shear direction of <112> are consistent with spinel-law twins. Inferred bulk shock pressures for the investigated samples, as constrained by planar deformation features (PDFs) in quartz and shock twins in zircon, range from 0 to 20 GPa; onset of shock-induced twinning in magnetite is observed at >5 GPa. These results highlight the utility of magnetite to record shock deformation in rocks that experience shock pressures >5 GPa, which may be useful in quartz-poor samples. Despite significant hydrothermal alteration and the variable transformation of host magnetite to hematite, shock effects are preserved, which demonstrates that magnetite is a reliable mineral for preserving shock deformation over geologic time.

Highlights

  • Magnetite, with an inverse spinel structure and nominal chemical formula of Fe23+Fe2+O42, is a common accessory mineral in igneous, sedimentary, and metamorphic rocks (e.g., Deer et al, 1992)

  • We report systematic electron backscatter diffraction crystallographic analysis of shock features in magnetite from a transect across the 52-km-diameter ca. 380 Ma Siljan impact structure in Sweden

  • Up to 10–20 magnetite grains were surveyed in each sample using backscattered electron (BSE) imaging, and orientation mapping using electron backscatter diffraction (EBSD) was conducted on two to six

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Summary

Introduction

With an inverse spinel structure and nominal chemical formula of Fe23+Fe2+O42–, is a common accessory mineral in igneous, sedimentary, and metamorphic rocks (e.g., Deer et al, 1992). Magnetite grains in granitoid samples contain brittle fracturing, crystal-plasticity, and lamellar twins. We used scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD) analysis to conduct a systematic assessment of shock microstructures in magnetite from the Siljan impact structure.

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