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Abstract
High-resolution emission spectra of IF from a corona-excited supersonic jet discharge are presented. Six vibrational bands of the D'2-A'2 transition were rotationally analyzed for the first time, as well as four bands of the EO + -XO + transition. A study of the Ω-type doubling observed for the high-J rotational levels of D' has provided estimates for the relative energy differences between the electronic origins of the first-tier ion-pair states
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