Abstract
The effect of molecular orientation on the branching of the chemiluminescent channels of the formation of the CN * (B), the CN * (A), and the CF 3 * radicals has been studied in the reaction of Ar * with the oriented CF 3 CN molecule. The branching ratio of the formation of the CF 3 * radical has been found to be very small compared to that of the CN * (B) and of the CN * (A) radicals. The CN-end attack has been observed to be more favorable than the CF 3 -end attack in the formation of CN * (B) and of CN * (A), and the steric asymmetries in the reaction are almost equal to each other
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