Abstract
The emission spectra of KCl:Pb2+ and KI:Pb2+ excited in the A-absorption band at various temperatures are reported. The temperature dependence of the decay time of the A-band emission from KCl:Pb2+ and KI:Pb2+ is also investigated. The results are interpreted in terms of a model that includes the Jahn-Teller effect, the spin-orbit interaction, and an additional perturbation caused by either a next-nearest neighbour or a nearest neighbour cation vacancy; the spin-orbit interaction is assumed to be stronger than the Jahn-Teller effect. The temperature dependence of the decay kinetics of both KCl:Pb2+ are well described by this model.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
