Abstract
A theoretical analysis of emission in oligo- p-phenylene vinylene herringbone aggregates shows that the radiative decay rate of the lower exciton band-edge can exceed that of a single molecule. Such superradiant H-aggregates require long-range orientational order and constructive interference between the off-axis molecular transition dipole moments. Excellent agreement with the experimental emission spectrum of p-distyrylbenzene nanoaggregates is obtained. Extensions are made to superradiant polymer aggregates, which could have important optical device applications.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
