Emission characteristics of intermediate volatility organic compounds from a Chinese gasoline engine under varied operating conditions: Influence of fuel, velocity, torque, rotational speed, and after-treatment device

Abstract

Improved measurement of new pollutants, particularly intermediate volatility organic compounds (IVOCs), is urgently needed due to the lack of emission data under various operating conditions and potential fuel switching for gasoline engines. This study focused on examining the emission characteristics of IVOCs and the formation of secondary organic aerosols (SOA) in a commercial gasoline direct injection (GDI) engine, considering different fuels and operating conditions. The key findings are as follows: (1) The emission factor (EF) of IVOCs ranged from 2.0 to 357.8 mg kg-fuel−1, with a median value of 87.9 mg kg-fuel−1. (2) IVOCs emission characteristics were influenced by the fuel type and engine operating conditions. The addition of ethanol resulted in a significant decrease in IVOCs emissions, while lower velocities and torques led to higher IVOCs emissions. (3) Ethanol-blended fuel scenarios (E10, E25) and CGPF (Pd/Rh catalytically coated gasoline particle filter)-equipped scenarios exhibited high proportions of oxygen-containing compounds like aliphatic alcohols, ethers, and carboxylic acids. (4) IVOCs exhibited a high potential for the formation of SOA, underscoring the importance of controlling IVOCs in future strategies to mitigate particulate matter pollution in China. These findings highlight the significance of smooth traffic flow and advancements in fuel types, engine technologies, and after-treatment designs to effectively control IVOC emissions and contribute to the realization of a carbon-neutral society.