Emergent structures in active block copolymer composites.

Abstract

Block copolymer melts offer unique templates to control the position and alignment of nanoparticles due to their ability to self-assemble into periodic ordered structures. Active particles are shown to coassemble with block copolymers leading to emergent organized structures. The block copolymer acts as a soft template that can control the self-propulsion of active particles, both for interface-segregated and selective nanoparticles. At moderate activities, active particles can form organized structures such as polarized trains or rotating vortices. At high activity, the contrast in the polymeric and colloidal timescales can lead to particle swarms with distorted block copolymer morphology, due to the competition between polymeric self-assembly and active Brownian self-propulsion.