Abstract

AbstractOver the past few decades, chemical vapor deposition (CVD) of [2.2]paracyclophanes has captured significant attention as an emergent technology, producing conformal, chemically pure, and pinhole‐free coatings for biomedical and industrial applications. Compelling examples range from functional CVD polymers to tailored nanostructures. In this work, the unique functional properties of polymers derived from [2.2]paracyclophanes are connected with emergent applications. Special attention is given to the function‐property relationships in the areas of electronic materials, biomaterials, and separation materials. A particular focus is to highlight the versatility of CVD polymerization to process these polymers.

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