Abstract
The ligand field transitions in the optical and near-infrared spectra of V(III) complexes with aminopolycarboxylato ligands (edta, tmdta) are analyzed based on the angular overlap model (AOM) approach. Results from both solid state and solution spectra lead to an explanation of the spectral differences between six- and seven-coordinate complexes, particularly in the near-infrared region. Structural and electronic effects responsible for the preference to a certain geometrical arrangement are discussed.
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