Elimination of free fatty acid from palm oil by adsorption process using a strong base anion exchange resin

Abstract

Deacidification is one of the important processes to obtain a suitable raw feedstock for the production of bio-transformer oil. This work proposed an alternative process for reducing the acidity of refined palm oil by adsorption of the free fatty acids (FFAs) using anion exchange resins (AER). The effect of the types of functional groups (tertiary amine and quaternary ammonium group) and the resin structure (gel and macroporous structure) of the commercially available resins were characterized and investigated for their adsorption ability. The adsorption kinetic and experimental conditions such as adsorption time, the moisture content in resin, and resin amount were studied. The gel-type strong-base anion exchange resins exhibited the best performance for the FFAs removal. This result suggests that the quaternary ammonium functional groups in the resin have a high dissociation capacity for anion exchange and the gel-type resins easily access by the FFAs molecules. The effect of types of functional groups is stronger than that of the resin structure. The adsorption mechanism mainly occurred via an ion exchange equilibrium rather than the hydrogen bond complex. The FFAs adsorption on the resins conformed to the pseudo-second-order kinetic model. Under optimum conditions (room temperature, atmospheric pressure, resin dosage of 0.4 wt%, and 8 h adsorption time), the Pall Tec PTA304 resin reduced the acidity in palm oil from 0.5 to 0.02 mg KOH/g with the adsorption capacity at the equilibrium of 589.5 mg/g, achieving approximately 95 % FFAs removal. The negative values of ΔGads0 and ΔHads0 demonstrated that the FFAs adsorption on the Pall Tec PTA304 resin was a spontaneous and exothermic process. This study provides an insight into the interactions between FFAs and anion exchange resins that is useful for further development of palm based bio-transformer oil.