Elimination of a Mixture of Microplastics Using Conventional and Detergent-Assisted Coagulation.

Abstract

The research described here investigated the suitability of coagulation process in the elimination of microplastics from tap water. The purpose of the study was to assess the effects of microplastic type (PE1, PE2, PE3, PVC1, PVC2, and PVC3), tap water pH (3, 5, 7, and 9), coagulant doses (0, 0.025, 0.05, 0.1 and 0.2 g/L), and microplastic concentration (0.05, 0.1, 0.15, and 0.2 g/L) on elimination efficiency with coagulation utilizing Al and Fe coagulants as well coagulation combined with a detergent (SDBS) addition. This work also explores the elimination of a mixture of two microplastics (PE and PVC) that are significant in terms of the environment. The effectiveness of conventional and detergent-assisted coagulation was calculated as a percentage. The fundamental characteristics of microplastics were also determined via LDIR analysis, and on the basis of these findings, particles that were more coagulation-prone were identified. The maximum reduction in MPs was achieved with tap water's neutral pH and a coagulant dosage of 0.05 g/L. The addition of SDBS increased the loss of the plastic microparticles' efficacy. A removal efficiency of greater than 95% (Al-coagulant) and 80% (Fe-coagulant) was achieved for each of the microplastics tested. The removal efficiency of the microplastic mixture with SDBS-assisted coagulation was obtained at a level of 95.92% (AlCl3·6H2O) and 98.9% (FeCl3·6H2O). After each coagulation procedure, the mean circularity and solidity of the unremoved particles increased. This confirmed that particles with irregular shapes are easier to completely remove.