Abstract

AbstractOverall rate constants for the removal of N2(A, v') by H2(X), F2(X) and H2C2O(X̄) were measured at T = 298 K in a fast flow reactor at constant injector position. N2(A) molecules in the vibrational states v' = 0, 1, 2, 3 were produced in the reaction of Ar(3P0,2) with N2(X) and detected by laser induced fluorescence (LIF) using the excitation of the first positive system of N2, B(3Πg)σ A(3Σ+u). The measured rate constants are: magnified imageThe rates of reactions (1), (2) and (3) and the reaction mechanisms are discussed.

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