Elementary Edge and Screw Dislocations Visualized at the Lattice Periodicity Level in the Smectic Phase of Colloidal Rods.

Abstract

Topological defects such as dislocations play a major role in science, from condensed matter and geophysics to cosmology. These line defects present in periodically ordered structures mediate phase transitions and determine many distinctive features of materials, from crystal growth to mechanical properties. However, despite theoretical predictions, the detailed structure of dislocations remains largely elusive. By using a model system of tip-labeled rod-shaped particles enabling improved resolution and contrast by optical microscopy, insitu visualization and quantitative characterization of elementary dislocations has been performed at the lattice periodicity level in a colloidal smectic phase. Thanks to the micrometer layer spacing, the displacement field around an edge dislocation has been experimentally established and compared with the profile predicted by elastic theory. The local morphology of screw dislocations has also been evidenced, with the determination of the core size as well as the chiral handedness of the defect. Self-diffusion experiments performed at the individual particle level reveal for the first time nematiclike or "melted" ordering of the defect core.