Abstract

The recent progress and current developments in element-specific detection for gas chromatography by atomic plasma emission spectroscopy are reviewed with emphasis on the applications of microwave-induced plasmas (MIPs) in capillary separations. A number of current applications of atmospheric-pressure MIP detection are then considered, including empirical formula measurement of cyclosiloxane pyrolyzates from silicones, ligand-exchange reactions of aluminum chelates, selectivity and sensitivity considerations in rhodium-specific detection, and dual-element detection for boron and iron in ferroceneboronate derivatives of diols.

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