Abstract
Electronic properties of Mn(acac)3 complex : a cyclic voltammetry and computational chemistry study Tris(acetylacetonato) Manganese(III) is a catalyst in alkyd paint. In this study, the electronic properties of Mn(acac)3 are determined by means of electrochemistry and computational chemistry. The optimised geometrical and electronic structure of Mn(acac)3 is calculated by means of computational chemistry, and electrochemistry is applied to measure the following reactions:MnIII(acac)3 - e- ⇆ MnIV(acac)3 MnIII(acac)3 + e- ⇆ MnII(acac)3
Highlights
Note: This abstract was presented at the ‘Studentesimposium in die Natuurwetenskappe 2011’, presented under the protection of the SuidAfrikaanse Akademie vir Wetenskap en Kuns
The symposium was held at the University of South Africa on 27–28 October 2011
The electronic properties of Mn(acac)3 are determined by means of electrochemistry and computational chemistry
Summary
Note: This abstract was presented at the ‘Studentesimposium in die Natuurwetenskappe 2011’, presented under the protection of the SuidAfrikaanse Akademie vir Wetenskap en Kuns. Affiliations: 1Department of Chemistry, University of the Free State, South Africa & Conradie, J., 2013, ‘Elektroniese eienskappe van die Mn(asas)3-kompleks: ’n Sikliese voltammetrie- en berekeningschemiestudie’, Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie 32(1), Art. The symposium was held at the University of South Africa on 27–28 October 2011.
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