Abstract
Solutions of ReS4- undergo electro-oxidation at 0.5 V vs Ag|AgCl to give black, amorphous ReS4 via a process that can be reversed at −0.9 V. The oxidative polymerization can also be effected chemically using either I2 or ferrocenium as oxidants. X-ray absorption spectroscopy (XAS) suggests that the phases Re2S7 and ReS4 are closely related structurally. The XAS data were calibrated with studies on [ReS4]- and crystalline ReS2. For both ReS4 and Re2S7 XAS data show the presence of both S2- and S22-, with S2- being less abundant than S22-. The presence of terminal sulfides (rReS ∼ 2.14 A) was ruled out by the EXAFS analysis. Variable temperature EXAFS studies showed that ReS4 and Re2S7 convert to ReS2 as anticipated from the results of TGA experiments. These considerations, when taken together with literature precedents, led to the reformulation of Re2S7 as ReV(S)1.5(S2)1, and correspondingly ReS4 is formulated as ReV(S)1(S2)1.5. These two materials are proposed to be members of a continuum of Re(S)1.5-1(S2...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.