Abstract

An attempt was made to synthesize organophosphorus compounds by a combination of homogeneous chemical reactions in the volume of the solution with heterogeneous electrochemical reactions taking place at the electrodes. It was found that opening of the strained P4 ring and formation of the whole product occurs as the result of sequential attack of nucleophilic and electrophilic components, formed respectively at the cathode and anode in undivided electrochemical cell.

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