Abstract

The present study was focused on investigation of electrokinetic behaviour of lecithin-stabilized oil/water emulsions in the presence of chitosan oligosaccharides (COS). The oligosaccharides give unique opportunity for precisely characterization of the properties of chitosan as a function of the degree of acetylation (DA) and degree of polymerization (DP) of the polymer. For the study were chosen well characterized ultra pure COS molecules with completely acetylated monomers and mixture of COS molecules with acetylated and deacetylated monomers. The obtained results confirmed experimentally for the first time, the suggestion for the predominant contribution of hydrophobic (at high DA) and electrostatic (at low DA) interactions between chitosan monomers and the lecithin-covered droplet surface.

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