Abstract
The oriented external electric field (OEEF) promoted phase transfer catalysis (PTC) reaction is reported for the first time. It was demonstrated experimentally that an OEEF can act as promoter or inhibitor for the phase transfer hydrogenation of acetophenone depending on its direction. Organic solvents showed differing influences on the reaction, attributed to different electrical conductivities. A non-linear dependence of product yield on OEEF potential was also discovered. This work presents a methodology for promoting PTC reactions in the absence of a chemical phase transfer agent and shows promise for significantly improving the performance of organic reactions in biphasic liquid systems.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
