Abstract
AbstractCeramic capacitors with high electrostatic energy storage performances have captured much research interest in latest years. Sodium bismuth titanate (Na0.5Bi0.5TiO3)‐based ferroelectric ceramics show great potential due to their environment‐friendly composition, high polarization, and excellent relaxor properties. However, the nonergodic relaxor state of Na0.5Bi0.5TiO3‐based ceramics hampers the decrement of remanent polarization, leading to poor energy storage performance. Herein, the (1 − x)Na0.5Bi0.5TiO3–xLa(Ni2/3Ta1/3)O3 ceramics were designed to generate the transformation between nonergodic and ergodic relaxor state. As a result, the ceramics exhibit improved dielectric relaxation, slim polarization–electric field loops, and flattened current–electric field curves due to highly dynamic polar nanoregions. Particularly, the 0.85Na0.5Bi0.5TiO3–0.15La(Ni2/3Ta1/3)O3 ceramics show large breakdown electric field Eb (345 kV/cm), high recoverable energy density Wrec (3.6 J/cm3), and efficiency η (80.6%), revealing potential applications in electrostatic energy storage.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.